Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamidato](2,2′-bipyridine)manganese(II)
نویسندگان
چکیده
The title compound, [Mn(C(10)H(9)N(4)O(2)S)(2)(C(10)H(8)N(2))], contains a distorted octa-hedral [Mn(sdz)(2)(bpy)] (sdz is the sulfadiazine anion and bpy is 2,2'-bipyridine) complex mol-ecule. A three-dimensional network is generated by N-H⋯N, N-H⋯O and C-H⋯O hydrogen bonds from the sulfadiazine ligands.
منابع مشابه
Bis[4-amino-N-(pyrimidin-2-yl-κN)benzenesulfonamidato-κN](4,4′-dimethyl-2,2′-bipyridine-κ2 N,N′)cadmium dimethylformamide disolvate
In the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(12)H(12)N(2))]·2C(3)H(7)NO, the Cd(II) ion lies on a twofold rotation axis, is six-coordinated by N atoms, and displays a trigonal-prismatic geometry arising from the two sulfadiazinate ligands and one 4,4'-dimethyl-2,2'-bipyridine ligand. Both ligands are bidentate and coordinate via their N atoms. The O and carbonyl C atoms of the dimethyl-f...
متن کاملBis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamidato](1,10-phenanthroline)nickel(II)
In the mononuclear title compound, [Ni(C(10)H(9)N(4)O(2)S)(2)(C(12)H(8)N(2))], the Ni(II) atom has a distorted octa-hedral coordination geometry comprising four N atoms from two 4-amino-N-(pyrimidin-2-yl)benzene-sulfonamidate ligands and two N atoms from a 1,10-phenanthroline ligand. In the crystal, mol-ecules are connected into a three-dimensional supra-molecular network via N-H⋯O hydrogen bon...
متن کاملtrans-Bis[4-amino-N-(pyrimidin-2-yl-κN)benzenesulfonamidato-κN]bis(N,N-dimethylformamide-κO)cobalt(II)
The title complex, [Co(C(10)H(9)N(4)O(2)S)(2)(C(3)H(7)NO)(2)], lies across an inversion center. The Co(II) atom is coordinated in a slightly distorted octa-hedral geometry by four N atoms from two bidentate 4-amino-N-(pyrimidin-2-yl)benzene-sulfonamidate (sulfadiazine) anions and two O atoms from two dimethyl-formamide (DMF) ligands. The dihedral angle between the benzene and pyrimidine rings i...
متن کاملtrans-Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamidato]dipyridinenickel(II) hemihydrate
The asymmetric unit of the title compound, [Ni(C(10)H(9)N(4)O(2)S)(2)(C(5)H(5)N)(2)]·0.5H(2)O, contains the distorted octa-hedral trans-[Ni(sdz)(2)(py)(2)] (sdz is the sulfadiazine anion and py is pyridine) complex mol-ecule and half of a water mol-ecule. A three-dimensional network is generated by N-H⋯O and O-H⋯O hydrogen bonds and C-H⋯O inter-actions between the complex and the water mol-ecules.
متن کاملAmphiphilic ruthenium sensitizers and their applications in dye-sensitized solar cells.
Amphiphilic ligands 4,4'-bis(1-adamantyl-aminocarbonyl)-2,2'-bipyridine (L(1)), 4,4'-bis[5-[N-[2-(3beta-cholest-5-en-3-ylcarbamate-N-yl)ethyl]aminocarbonyl]]-2,2'-bipyridine (L(2)), 4,4'-bis[5-[N-[2-(3beta-cholest-5-en-3-ylcarbamate-N-yl)propyl]aminocarbonyl]]-2,2'-bipyridine (L(3)), and 4,4'-bis(dodecan-12-ol)-2,2'-bipyridine (L(4)) and their heteroleptic ruthenium(II) complexes of the type [R...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010